2007 - Jake Peavy-x, San Diego
2006 - Brandon Webb, Arizona
2005 - Chris Carpenter, St. Louis
2004 - Roger Clemens, Houston
2003 - Eric Gagne, Los Angeles
2002 - Randy Johnson-x, Arizona
2001 - Randy Johnson, Arizona
2000 - Randy Johnson, Arizona
1999 - Randy Johnson, Arizona
1998 - Tom Glavine, Atlanta
1997 - Pedro Martinez, Montreal
1996 - John Smoltz, Atlanta
1995 - Greg Maddux-x, Atlanta
1994 - Greg Maddux-x, Atlanta
1993 - Greg Maddux, Atlanta
1992 - Greg Maddux, Chicago
1991 - Tom Glavine, Atlanta
1990 - Doug Drabek, Pittsburgh
1989 - Mark Davis, San Diego
1988 - Orel Hershiser-x, Los Angeles
1987 - Steve Bedrosian, Philadelphia
1986 - Mike Scott, Houston
1985 - Dwight Gooden-x, New York
1984 - Rick Sutcliffe-x, Chicago
1983 - John Denny, Philadelphia
1982 - Steve Carlton, Philadelphia
1981 - Fernando Valenzuela, Los Angeles
1980 - Steve Carlton, Philadelphia
1979 - Bruce Sutter, Chicago
1978 - Gaylord Perry, San Diego
1977 - Steve Carlton, Philadelphia
1976 - Randy Jones, San Diego
1975 - Tom Seaver, New York
1974 - Mike Marshall, Los Angeles
1973 - Tom Seaver, New York
1972 - Steve Carlton-x, Philadelphia
1971 - Ferguson Jenkins, Chicago
1970 - Bob Gibson, St. Louis
1969 - Tom Seaver, New York
1968 - Bob Gibson-x, St. Louis
1967 - Mike McCormick, San Francisco
1966 - Sandy Koufax-x, Los Angeles
1965 - Sandy Koufax-x, Los Angeles
1963 - Sandy Koufax-x, Los Angeles
1962 - Don Drysdale, Los Angeles
1960 - Vernon Law, Pittsburgh
1957 - Warren Spahn, Milwaukee Braves
1956 - Don Newcombe, Brooklyn
NOTE: From 1956-1966 there was one selection from both leagues.
x-Unanimous choice

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